I have built entire web sites in Django. Web apps and such. I know my way around CSS, HTML, and Javascript for making things pretty. Though primarily I'm a programmer so I can also handle backend work. My last job was at company where people could come in and hire us to do custom web apps. Most people wanted Django but I've also done stuff like Node and Android development.
I have not, but I did give it a good look and looks pretty straight forward with PHP. I can imagine any ideas you might have for custom add-ons must be more on the complex side of things. I wouldn't be against giving it a shot though. I'm a language agnostic programmer, though I have done work with PHP before.
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